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air separation unit

Air separation unit

Air Separation Units (ASU) liquefies air via compression-cycle deep-freezing, then precisely separates oxygen, nitrogen, argon, etc., by boiling point differences, consistently producing gases over 99.999% pure and simultaneously extracting rare gases like neon, krypton, xenon. Ideal for traditional metallurgical oxy-fuel combustion, new coal-to-chemical ammonia synthesis, and large-scale nitrogen fertilizer production, the ASU not only meets large-scale industries’ continuous gas demand but also showcases YUEQIN’s technical strength and global engineering project implementation capabilities.

Air separation methods

Cryogenic Distillation

Cryogenic distillation first cools air to liquefy it, then selectively separates its components based on their boiling point differences through distillation. This produces high-purity gas, but it consumes a lot of energy. The system requires tightly integrated heat exchangers and separation columns to maintain efficiency, with refrigeration energy coming from the inlet air compressor.
To achieve low temperatures, air separation plants employ two refrigeration cycles: utilizing isothermal throttling via a throttling device, or isentropic expansion via an expander. Cryogenic equipment must be housed in a “cold box” (insulated enclosure) to minimize cooling losses.

Other Air Separation Methods

  • Membrane separation technology: Low energy consumption and flexible parameters. Room-temperature polymer membranes produce 25%-50% oxygen-enriched air; ceramic membranes (ITM and OTM) require temperatures of 800-900°C and can produce high-purity oxygen exceeding 90%. They can be used to produce oxygen-depleted or nitrogen-enriched gas for passenger aircraft fuel tanks to reduce risk, and can also provide oxygen-enriched air for pilots of high-altitude, unpressurized aircraft.
  • Pressure Swing Adsorption (PSA): Operating at room temperature and requiring no liquefaction, PSA uses zeolite (a “molecular sponge”) for high-pressure adsorption and reduced-pressure desorption to separate oxygen and nitrogen. This compact compressor can be used to manufacture portable medical oxygen concentrators. Vacuum Pressure Swing Adsorption (VPSA) is similar, with only the target gas being desorbed at subatmospheric pressure.

Air Separation Unit (ASU) Operation Process and Core Components

The compressed air from the air compressor is first cooled by an air pre-cooling system before being removed by molecular sieves to remove impurities such as moisture, carbon dioxide, and hydrocarbons. The purified air is then split into two paths: one is sent directly to the upper column of the distillation tower, while the other is expanded and cooled by an expander before being sent to the lower column. Within the distillation tower, the rising vapor and the falling liquid undergo heat exchange and separation, ultimately producing high-purity nitrogen at the top of the upper column and high-purity oxygen at the bottom.

Compression System

Comprising an air inlet filter (to filter dust), an air compressor (to pressurize air), an air compressor interstage cooler (to reduce temperature and maintain efficiency), and an air compressor vent silencer (to reduce noise).

Pre-cooling System
Comprising a water-cooling tower, an air-cooling tower (to exchange heat and reduce temperature), a water pump (to provide cooling water), and a chiller (to provide deep cooling).

Purification System
The core is a molecular sieve adsorber (to remove impurities) coupled with a nitrogen vent silencer (to reduce exhaust noise).

Heat Exchange System

Includes the main heat exchanger (for heat exchange between air and low-temperature gas to reduce temperature) and the subcooler (for cooling liquid products to reduce vaporization losses).

Distillation System
Includes the distillation tower (for gas-liquid contact separation) and the condenser-evaporator (for maintaining the distillation cycle).

Product Delivery System

Comprising a pressure regulating station (for pressure regulation) and a metering station (for flow measurement).

Liquid Storage Backup System

Includes liquid storage tanks (for storing liquid oxygen and liquid nitrogen), gas storage tanks (for buffering gaseous products), and a liquid evaporator (for emergency liquid-to-gas conversion).

Working Principle of an Air Separation Unit (ASU)

Although air separation units can utilize a variety of technologies, such as membrane separation and pressure swing adsorption, cryogenic fractionation (distillation) remains the mainstream core technology for achieving efficient, high-purity separation. Its typical operation process is divided into four key stages:

1. Compression Stage

Atmospheric air is first drawn into the ASU and then enters a multi-stage compressor system for pressurization. The core purpose of this stage is to increase the air pressure, thereby reducing energy consumption and improving efficiency in the subsequent cooling and separation processes. The air pressure is typically controlled within a range of 5-10 barg, laying the foundation for subsequent processes.

2. Purification Stage

The pressurized air first passes through a purification system to remove impurities, primarily moisture, carbon dioxide, and trace amounts of oil, dust, and other pollutants. This step is crucial: it ensures the high purity of the final output gas, meeting the requirements of industrial and medical applications; it also prevents impurities from freezing or accumulating in the subsequent low-temperature environment, preventing blockage of heat exchangers, pipelines, and other equipment, thereby ensuring stable operation of the unit.

3. Cooling Stage

The purified compressed air enters a cooling system consisting of a heat exchanger and a refrigeration cycle, where it is gradually cooled to a low temperature. Since cryogenic fractionation is based on the differences in boiling points between gaseous components, the cooling process lowers the air to its liquefaction temperature, converting the gaseous air into liquid air, preparing it for subsequent distillation separation.

4. Separation Stage

Liquid air is fed into a single- or multi-stage distillation tower, where its components are separated through fractional distillation. The differences in boiling points between the gases are crucial for separation: nitrogen, with its lowest boiling point, vaporizes and rises from the liquid air first, being collected at the top of the tower. Oxygen, with its higher boiling point, remains at the bottom of the tower and is discharged as a liquid or gas. If argon needs to be separated, since its boiling point lies between nitrogen and oxygen, it can be extracted from the middle of the tower through a specialized distillation section.

Application

  • Medical Healthcare
  • Industrial Manufacturing
  • Food and Beverages
  • Energy production

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